Low-E Coating
Low-E is short for low emissivity coating. This type of coating is typically used on one inner surface of a double or triple glazing unit. Looking at the spectrum of electromagnetic waves it is clear that a low-e coating should be pass-filter: |
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| All sputtered Low-E coatings are based on a thin, closed but transparent silver layer. This thin layer of 5nm to 20nm thickness acts as an infrared mirror. Silver is the metal with the best electrical and thermal conductivity. Alternatively gold or copper could be used, but both of them are not a thin as a comparable silver layer. For that reason it is nearly impossible to compensate the absorbance colours of these layers by other dielectric layers. The high transmission of a low-e film is the next problem with other IR-mirrors than silver. Silver is a weak and soft material that tends to oxidize and agglomerate at higher temperatures. The pure silver layer needs to be protected and the optical appearance has to be tuned to a neutral colour. Therefore other layers are needed for the full layer stack. At least a dielectric layer between the silver and the glass substrate is necessary as well as a second one on top of the silver. The first commercial systems of this type were introduced by ASAHI in the late 80ties: Glass-ZnO-Ag-ZnO and alternatively Glass-ITO-Ag-ITO (so called IMI-Layers). Before two pieces of glass come together in a double glazing unit both substrates are needed to be washed. The coating has to survive the washing procedure and it has to last fore decades inside the double glazing (in an Ar- or Kr-atmosphere). The Low-E layer has to fulfil a certain mechanical and chemical stability. That causes protective and adhesive layers inside the layer stack to strengthen the silver layer. Especially oxides were used for dielectric layers, sputtered in an aggressive oxygen atmosphere, which normally oxidises the silver layer. Thin metallic or suboxidic layers were introduced to capture the oxygen and protect the silver. NiCr, Cr, Ti, Nb and the sub oxides are commonly used for this purpose. |
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Machines |
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ApollonHorizontal in-line sputter coating plant for architectural glass more... |
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Detailed Information |
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Thick silver layers reflect the infrared light pretty good, but they also absorb a high amount of the visible spectrum. The goal was to minimize this visible absorption by keeping the conductivity constant. more... |
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Blue Line: Transmission